Functional Coatings  
Transparent and Conductive Electrodes
Barrier Electrode Substrates
Wet Coating and Printing (CCC)
Protection Layer for Ultrathin Glass Foils
Multifunctional Glues
Jun Funori

Transparent and Conductive Electrodes

The development of highly conductive and transparent interface materials and their application in organic optoelectronic devices is an important research topic. One challenge is to develop new materials that compete or outperform the commonly used ITO in terms of costs, transparency, electrical resistance and resistance to cracking when bent. Another challenge is that thin films of such materials can be deposited at low temperatures by large-area compatible coating methods on flexible substrates. The development of highly conductive and transparent materials with improved properties will increase the device performance and lower the industrial production costs. Such materials are interesting for organic solar cells, displays and light-emitting devices, and for transparent electronics in general. In a running CCEM-CH project (CONNECT-PV) we are developing flexible and transparent electrodes that can be applied by lamination.

Together with our industrial partner Sefar AG, we have introduced a flexible, stable and transparent electrode for OPV cells consisting of polymer fibres and current-collecting metal wires woven into a mesh. To provide a stable support for the thin OPV active film (~ 150 nm), the holes in the mesh structure (~ 0.07 mm2) were filled with a curable transparent polymer emulsion in such a way that one side of the fabric was fully embedded in the polymer, while metal wires were exposed by  ~ 10-15 micrometers to air at the other side. We fabricated woven fabric/PEDOT:PSS(~ 1-1.5 micrometers)/P3HT:PCBM/Al solar cells with an efficiency = 2.2%, and demonstrated that the photocurrent can be transported practically loss-free over a distance of several cm at least, a relevant distance for a large-area OPV cell applications. We then showed that the OPV performance using the woven fabric electrode can be considerably improved (efficiency = 3.1%) by further decreasing the distance (~ 5 micrometers) between the protruding metal wires and the plane of the polymer-filled holes. For reduced metal wire exposure, thinner but still covering PEDOT:PSS layers could be used; this resulted in increased light transmittance reaching the active layer, and translated in an associated increase in the short-circuit current density and efficiency. The production of the woven substrate electrode is fully integrated into a technological R2R process (fabric width 120 cm, 10 meters per minute) at Sefar AG. This substrate electrode is further developed and used in a running EU project.

 

The picture shows an organic solar cell fabricated on a woven mesh electrode.

References:

W. Kylberg et al., Adv. Mater. 2011, 23, 1015 ;  W. Kylberg et al., Prog. Photovolt: Res. Appl. 2013, 21, 652.

Ihre Ansprechpersonen:

Dr. Roland Hany

 


 

 

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